南方科技大学知识苑(SUSTech KC): Anionic Chemistry Modulation Enabled Environmental Self-Charging Aqueous Zinc Batteries: The Case of Carbonate Ions

题名	Anionic Chemistry Modulation Enabled Environmental Self-Charging Aqueous Zinc Batteries: The Case of Carbonate Ions
作者	Qu, Guangmeng 1; Wang, Lu 1; Zhao, Yongzheng 1; Wang, Dedong 1; Zhang, Xixi 2; Wang, Bin 1; Wang, Fengbo 1; Jing, Zhongxin 1; Xu, Xijin 2; Xu, Liqiang 1; Li, Hongfei3
通讯作者	Xu, Liqiang; Li, Hongfei
发表日期	2024-08-01
DOI	10.1002/anie.202409774
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 影响因子和分区
ISSN	1433-7851
EISSN	1521-3773
摘要	["Anionic chemistry modulation represents a promising avenue to enhance the electrochemical performance and unlock versatile applications in cutting-edge energy storage devices. Herein, we propose a methodology that involves anionic chemistry of carbonate anions to tailor the electrochemical oxidation-reduction reactions of bismuth (Bi) electrodes, where the conversion energy barrier for Bi (0) to Bi (III) has been significantly reduced, endowing anionic full batteries with enhanced electrochemical kinetics and chemical self-charging property. The elaborately designed batteries with an air-switch demonstrate rapid self-recharging capabilities, recovering over 80 % of the electrochemical full charging capacity within a remarkably short timeframe of 1 hour and achieving a cumulative self-charging capacity of 5 Ah g-1. The aqueous self-charging battery strategy induced by carbonate anion, as proposed in this study, holds the potential for extending to various anionic systems, including seawater-based Cl- ion batteries. This work offers a universal framework for advancing next-generation multi-functional power sources.","A methodology that involves anionic chemistry of carbonate anions to tailor the electrochemical oxidation-reduction reactions of bismuth (Bi) electrodes is presented, where the conversion energy barrier for Bi (0) to Bi (III) has been significantly reduced, endowing anionic full batteries with enhanced electrochemical kinetics and chemical self-charging property. image"]
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
资助项目	National Natural Science Foundation of China["22071135","22371167","22379062"] ; Natural Science Foundation of Shandong Province["ZR2022ZD29","ZR2020MB081"] ; China Postdoctoral Science Foundation[2023M742053] ; Shenzhen Stable Support Plan Program for Higher Education Institutions Research Program[20220816131408001] ; Shenzhen Science and Technology Program["JCYJ20230807091802006","JCYJ20220818100405012"] ; Guangdong Basic and Applied Basic Research Foundation["2022A0505050015","2021B1515120004"]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001293014300001
出版者	WILEY-V C H VERLAG GMBH
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：4
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/804689
专题	工学院_系统设计与智能制造学院
作者单位	1.Shandong Univ, Sch Chem & Chem Engn, Key Lab Colloid & Interface Chem, Minist Educ, Jinan 250100, Shandong, Peoples R China 2.Univ Jinan, Sch Phys & Technol, Jinan 250022, Shandong, Peoples R China 3.Southern Univ Sci & Technol, Sch Syst Design & Intelligent Mfg, Shenzhen 518055, Guangdong, Peoples R China
通讯作者单位	系统设计与智能制造学院
推荐引用方式 GB/T 7714	Qu, Guangmeng,Wang, Lu,Zhao, Yongzheng,et al. Anionic Chemistry Modulation Enabled Environmental Self-Charging Aqueous Zinc Batteries: The Case of Carbonate Ions[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024.
APA	Qu, Guangmeng.,Wang, Lu.,Zhao, Yongzheng.,Wang, Dedong.,Zhang, Xixi.,...&Li, Hongfei.(2024).Anionic Chemistry Modulation Enabled Environmental Self-Charging Aqueous Zinc Batteries: The Case of Carbonate Ions.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Qu, Guangmeng,et al."Anionic Chemistry Modulation Enabled Environmental Self-Charging Aqueous Zinc Batteries: The Case of Carbonate Ions".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024).