南方科技大学知识苑(SUSTech KC): Synthesis of Bridged Five-Membered Ring Systems by Type II [3+2] Annulation of Allenylsilane-ene

题名	Synthesis of Bridged Five-Membered Ring Systems by Type II [3+2] Annulation of Allenylsilane-ene
作者	Li, Ling-Zi1 ; Huang, Yu-Rou1 ; Xu, Zi-Xun 1; He, Hong-Sen 1; Ran, Hong-Wei1 ; Zhu, Ke-Yu 1; Han, Jing-Chun1,2 ; Li, Chuang-Chuang1,2
通讯作者	Han, Jing-Chun; Li, Chuang-Chuang
发表日期	2024-08-29
DOI	10.1021/jacs.4c09384
发表期刊	JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 影响因子和分区
ISSN	0002-7863
EISSN	1520-5126
卷号	146 期号:36
摘要	The first type II intramolecular [3 + 2] annulation of allenylsilane-ene has been achieved, enabling diastereoselective and efficient construction of synthetically challenging bridged five-membered ring systems such as bicyclo[3.2.1]. This mild and direct process shows a broad substrate scope and is highly stereospecific. Particularly, this work represents the first stereoselective method for the direct synthesis of bicyclo[3.2.1] ring systems from acyclic precursors. Additionally, the first asymmetric total syntheses of (+)- and (-)-strepsesquitriol, and the efficient formation of the synthetically challenging tetracyclic core of pierisjaponol D are achieved by this type II [3 + 2] annulation reaction.
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China["22225102","22371114"] ; National Key R&D Program of China[2022YFE0205500] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515011198] ; Shenzhen Bay Laboratory[SZBL2021080601005] ; Shenzhen Science and Technology Program["JCYJ20220818100603008","JCYJ20210324104408023","JCYJ20210324105202006"]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001308479400001
出版者	AMER CHEMICAL SOC
来源库	Web of Science
引用统计
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/828888
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Guangming Adv Res Inst, Dept Chem, Shenzhen 518055, Peoples R China 2.Shenzhen Bay Lab, Shenzhen 518132, Peoples R China
第一作者单位	化学系; 深圳格拉布斯研究院
通讯作者单位	化学系; 深圳格拉布斯研究院
第一作者的第一单位	化学系; 深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Li, Ling-Zi,Huang, Yu-Rou,Xu, Zi-Xun,et al. Synthesis of Bridged Five-Membered Ring Systems by Type II [3+2] Annulation of Allenylsilane-ene[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2024,146(36).
APA	Li, Ling-Zi.,Huang, Yu-Rou.,Xu, Zi-Xun.,He, Hong-Sen.,Ran, Hong-Wei.,...&Li, Chuang-Chuang.(2024).Synthesis of Bridged Five-Membered Ring Systems by Type II [3+2] Annulation of Allenylsilane-ene.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,146(36).
MLA	Li, Ling-Zi,et al."Synthesis of Bridged Five-Membered Ring Systems by Type II [3+2] Annulation of Allenylsilane-ene".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 146.36(2024).