南方科技大学知识苑(SUSTech KC): Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of Î²-Ketoesters

题名	Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of Î²-Ketoesters
作者	Guo, Yonghong 1; Zhao, Jiayi2,3 ; Zu, Bing2,3 ; He, Chuan 2,3
通讯作者	He, Chuan
发表日期	2024-09-01
DOI	10.1055/a-2402-6757
发表期刊	SYNTHESIS-STUTTGART 影响因子和分区
ISSN	0039-7881
EISSN	1437-210X
摘要	A novel bifunctional photocatalyst combining an aza-BODIPY and a chiral oxazoline has been developed. This photocatalyst enables the asymmetric hydroxylation of beta-ketoesters under an oxygen atmosphere and irradiation with 18-W red LEDs. This procedure offers a convenient and potentially general approach to obtain enantioenriched alpha-hydroxy-beta-dicarbonyl products. The results reported in this manuscript demonstrate the promise of this new organic photocatalyst design and will help expand the application of BODIPY-based chiral photocatalysts.
关键词	bifunctional photocatalyst aza-BODIPY asymmetric catalysis beta-ketoesters red-light photocatalysis
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	通讯
资助项目	National Natural Science Foundation of China["22122102","22271134"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Guangdong Pearl River Talent Program[2019QN01Y628] ; Shenzhen Science and Technology Innovation Commission["RCJC20221008092723013","JCYJ20230807093104009"] ; Hebei Province Innovation Capability Enhancement Plan Project[22567632H]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:001320635800002
出版者	GEORG THIEME VERLAG KG
来源库	Web of Science
引用统计
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/834307
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Hebei Univ, Coll Chem & Mat Sci, Key Lab Med Chem & Mol Diag, Key Lab Chem Biol Hebei Prov, Baoding 071002, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China
通讯作者单位	深圳格拉布斯研究院; 化学系
推荐引用方式 GB/T 7714	Guo, Yonghong,Zhao, Jiayi,Zu, Bing,et al. Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of Î²-Ketoesters[J]. SYNTHESIS-STUTTGART,2024.
APA	Guo, Yonghong,Zhao, Jiayi,Zu, Bing,&He, Chuan.(2024).Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of Î²-Ketoesters.SYNTHESIS-STUTTGART.
MLA	Guo, Yonghong,et al."Aza-BODIPY-Based Bifunctional Photocatalyst for Red-Light-Driven Asymmetric Hydroxylation of Î²-Ketoesters".SYNTHESIS-STUTTGART (2024).