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Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).","jscount":"1","jsurl":"/simple-search?field1=dc.contributor.author&rpp=10&accurate=true&advanced=false&sort_by=-1&isNonaffiliated=false&search_type=-1&query1=%2522Yu%252C%2BXiaofang%2522&order=desc&&fq=dc.project.title_filter%3ASupporting%5C+matrixes%5C+play%5C+an%5C+important%5C+role%5C+in%5C+Cu%5C-based%5C+catalyst%5C%2FNORR.%5C+Commonly%5C+used%5C+supporting%5C+matrixes%5C+for%5C+Cu%5C-based%5C+catalysts%5C+include%5C+Ni%5C+foams%5C+%5C%28NF%5C%29%2C%5C+Cu%5C+foams%5C+%5C%28CF%5C%29%2C%5C+carbon%5C+felts%2C%5C+graphite%5C+felts%2C%5C+glassy%5C+carbon%5C+%5C%28GCE%5C%29%2C%5C+carbon%5C+clothes%5C+%5C%28CC%5C%29%2C%5C+and%5C+carbon%5C+paper%2C%5C+which%5C+protect%5C+and%5C+support%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%2C125%2C165%2C209%5C%5D.%5C+However%2C%5C+in%5C+NORR%2C%5C+researchers%5C+have%5C+focused%5C+on%5C+Cu%5C-based%5C+catalysts%2C%5C+ignoring%5C+the%5C+influence%5C+and%5C+role%5C+of%5C+supporting%5C+matrixes.%5C+Currently%2C%5C+only%5C+Li%27%27s%5C+team%5C+has%5C+published%5C+a%5C+paper%5C+on%5C+the%5C+effect%5C+of%5C+three%5C+different%5C+supporting%5C+matrixes%5C+%5C%28NF%2C%5C+CF%5C+and%5C+CC%5C%29%5C+on%5C+the%5C+NORR%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%5C%5D.%5C+They%5C+prepared%5C+three%5C+electrodes%2C%5C+Cu%40NF%2C%5C+Cu%40CF%5C+and%5C+Cu%40CC%2C%5C+by%5C+supporting%5C+Cu%5C-based%5C+catalysts%5C+onto%5C+NF%2C%5C+CF%5C+and%5C+CC%5C+by%5C+electrodeposition.%5C+Among%5C+them%2C%5C+the%5C+surface%5C+morphology%5C+of%5C+Cu%40NF%5C+showed%5C+a%5C+uniform%5C+dendrite%5C+structure.%5C+When%5C+CF%5C+and%5C+CC%5C+were%5C+used%5C+as%5C+support%2C%5C+agglomeration%5C+of%5C+Cu%5C-based%5C+catalysts%5C+occurred.%5C+In%5C+addition%2C%5C+electrochemical%5C+experiments%5C+and%5C+DFT%5C+showed%5C+that%5C+Ni%5C+atoms%5C+have%5C+strong%5C+adsorption%5C+capacity%5C+for%5C+H%2C%5C+and%5C+NF%5C+can%5C+introduce%5C+Ni%5C+atoms%5C+into%5C+Cu%5C-based%5C+catalysts%5C+to%5C+promote%5C+the%5C+generation%5C+of%5C+H%2C%5C+reduce%5C+the%5C+overpotential%2C%5C+and%5C+make%5C+NO%E2%88%92%5C+reduce%5C+rapidly%5C+through%5C+the%5C+H%5C+pathway.%5C+Therefore%2C%5C+the%5C+order%5C+of%5C+electrocatalytic%5C+activities%5C+of%5C+the%5C+Cu%5C+catalysts%5C+formed%5C+on%5C+the%5C+three%5C+supports%5C+is%5C+Cu%40NF%5C+%3E%5C+Cu%40CF%5C+%3E%5C+Cu%40CC.%5C+The%5C+reason%5C+for%5C+the%5C+superiority%5C+of%5C+Cu%40CF%5C+over%5C+Cu%40CC%5C+is%5C+the%5C+good%5C+electronic%5C+conductivity%5C+of%5C+CF.%5C+In%5C+summary%2C%5C+we%5C+can%5C+preliminarily%5C+conclude%5C+that%5C+supporting%5C+matrixes%5C+may%5C+affect%5C+the%5C+surface%5C+morphology%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+can%5C+influence%5C+the%5C+reaction%5C+path%5C+under%5C+specific%5C+conditions%5C+%5C%28Fig.%5C+5%5C%29.%5C+There%5C+is%5C+no%5C+relevant%5C+research%5C+on%5C+how%5C+supporting%5C+matrixes%5C+affect%5C+the%5C+morphology%2C%5C+structure%2C%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+what%5C+role%5C+they%5C+play%5C+in%5C+NORR.%5C+Meanwhile%2C%5C+there%5C+is%5C+a%5C+lack%5C+of%5C+relevant%5C+studies%5C+to%5C+distinguish%5C+between%5C+them.This%5C+work%5C+was%5C+financially%5C+supported%5C+by%5C+the%5C+National%5C+Natural%5C+Science%5C+Foundation%5C+of%5C+China%5C+%5C%28Project%5C+No.%5C+22266009%5C%29%5C%3B%5C+Guizhou%5C+Science%5C+and%5C+Technology%5C+Plan%5C+Project%5C+%5C%28Guizhou%5C+Science%5C+Support%5C+%5C%5B2024%5C%5D%5C+General%5C+118%5C%29%5C%3B%5C+Doctoral%5C+Research%5C+Fund%5C+of%5C+Guizhou%5C+Normal%5C+University%2C%5C+China%5C+%5C%28GZNUD%5C+%5C%5B2019%5C%5D6%5C%29."},{"jsname":"lastIndexed","jscount":"2025-04-25"}],"资助项目","dc.project.title_filter")'>资助项目

Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).","jscount":"1","jsurl":"/simple-search?field1=dc.contributor.author&rpp=10&accurate=true&advanced=false&sort_by=-1&isNonaffiliated=false&search_type=-1&query1=%2522Yu%252C%2BXiaofang%2522&order=desc&&fq=dc.project.title_filter%3ASupporting%5C+matrixes%5C+play%5C+an%5C+important%5C+role%5C+in%5C+Cu%5C-based%5C+catalyst%5C%2FNORR.%5C+Commonly%5C+used%5C+supporting%5C+matrixes%5C+for%5C+Cu%5C-based%5C+catalysts%5C+include%5C+Ni%5C+foams%5C+%5C%28NF%5C%29%2C%5C+Cu%5C+foams%5C+%5C%28CF%5C%29%2C%5C+carbon%5C+felts%2C%5C+graphite%5C+felts%2C%5C+glassy%5C+carbon%5C+%5C%28GCE%5C%29%2C%5C+carbon%5C+clothes%5C+%5C%28CC%5C%29%2C%5C+and%5C+carbon%5C+paper%2C%5C+which%5C+protect%5C+and%5C+support%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%2C125%2C165%2C209%5C%5D.%5C+However%2C%5C+in%5C+NORR%2C%5C+researchers%5C+have%5C+focused%5C+on%5C+Cu%5C-based%5C+catalysts%2C%5C+ignoring%5C+the%5C+influence%5C+and%5C+role%5C+of%5C+supporting%5C+matrixes.%5C+Currently%2C%5C+only%5C+Li%27%27s%5C+team%5C+has%5C+published%5C+a%5C+paper%5C+on%5C+the%5C+effect%5C+of%5C+three%5C+different%5C+supporting%5C+matrixes%5C+%5C%28NF%2C%5C+CF%5C+and%5C+CC%5C%29%5C+on%5C+the%5C+NORR%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%5C%5D.%5C+They%5C+prepared%5C+three%5C+electrodes%2C%5C+Cu%40NF%2C%5C+Cu%40CF%5C+and%5C+Cu%40CC%2C%5C+by%5C+supporting%5C+Cu%5C-based%5C+catalysts%5C+onto%5C+NF%2C%5C+CF%5C+and%5C+CC%5C+by%5C+electrodeposition.%5C+Among%5C+them%2C%5C+the%5C+surface%5C+morphology%5C+of%5C+Cu%40NF%5C+showed%5C+a%5C+uniform%5C+dendrite%5C+structure.%5C+When%5C+CF%5C+and%5C+CC%5C+were%5C+used%5C+as%5C+support%2C%5C+agglomeration%5C+of%5C+Cu%5C-based%5C+catalysts%5C+occurred.%5C+In%5C+addition%2C%5C+electrochemical%5C+experiments%5C+and%5C+DFT%5C+showed%5C+that%5C+Ni%5C+atoms%5C+have%5C+strong%5C+adsorption%5C+capacity%5C+for%5C+H%2C%5C+and%5C+NF%5C+can%5C+introduce%5C+Ni%5C+atoms%5C+into%5C+Cu%5C-based%5C+catalysts%5C+to%5C+promote%5C+the%5C+generation%5C+of%5C+H%2C%5C+reduce%5C+the%5C+overpotential%2C%5C+and%5C+make%5C+NO%E2%88%92%5C+reduce%5C+rapidly%5C+through%5C+the%5C+H%5C+pathway.%5C+Therefore%2C%5C+the%5C+order%5C+of%5C+electrocatalytic%5C+activities%5C+of%5C+the%5C+Cu%5C+catalysts%5C+formed%5C+on%5C+the%5C+three%5C+supports%5C+is%5C+Cu%40NF%5C+%3E%5C+Cu%40CF%5C+%3E%5C+Cu%40CC.%5C+The%5C+reason%5C+for%5C+the%5C+superiority%5C+of%5C+Cu%40CF%5C+over%5C+Cu%40CC%5C+is%5C+the%5C+good%5C+electronic%5C+conductivity%5C+of%5C+CF.%5C+In%5C+summary%2C%5C+we%5C+can%5C+preliminarily%5C+conclude%5C+that%5C+supporting%5C+matrixes%5C+may%5C+affect%5C+the%5C+surface%5C+morphology%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+can%5C+influence%5C+the%5C+reaction%5C+path%5C+under%5C+specific%5C+conditions%5C+%5C%28Fig.%5C+5%5C%29.%5C+There%5C+is%5C+no%5C+relevant%5C+research%5C+on%5C+how%5C+supporting%5C+matrixes%5C+affect%5C+the%5C+morphology%2C%5C+structure%2C%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+what%5C+role%5C+they%5C+play%5C+in%5C+NORR.%5C+Meanwhile%2C%5C+there%5C+is%5C+a%5C+lack%5C+of%5C+relevant%5C+studies%5C+to%5C+distinguish%5C+between%5C+them.This%5C+work%5C+was%5C+financially%5C+supported%5C+by%5C+the%5C+National%5C+Natural%5C+Science%5C+Foundation%5C+of%5C+China%5C+%5C%28Project%5C+No.%5C+22266009%5C%29%5C%3B%5C+Guizhou%5C+Science%5C+and%5C+Technology%5C+Plan%5C+Project%5C+%5C%28Guizhou%5C+Science%5C+Support%5C+%5C%5B2024%5C%5D%5C+General%5C+118%5C%29%5C%3B%5C+Doctoral%5C+Research%5C+Fund%5C+of%5C+Guizhou%5C+Normal%5C+University%2C%5C+China%5C+%5C%28GZNUD%5C+%5C%5B2019%5C%5D6%5C%29."},{"jsname":"lastIndexed","jscount":"2025-04-25"}],"资助项目","dc.project.title_filter")'>

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Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).'>Supporting matrixes play an important role in...[1]

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[1] Calcyclin-binding protein contributes to cholangiocarcinoma progression by inhibiting ubiquitination of MCM2 来源：ONCOLOGY RESEARCH, 2023, 卷号: 31, 期号: 3 作者： Zhang, Yusen; Liu, Liping; Luo, Biwei; Tang, Honggui; Yu, Xiaofang; et al. 浏览/下载:0/0被引[WOS]:3被引[Scopus]:3影响因子:2.0期刊论文SCI 评论分享收藏
[2] Preparation, characterization, and application of Cu-based catalysts in electrocatalytic reduction of nitrate: A review 来源：Materials Today Chemistry, 2024, 卷号: 41 作者： Chen, Yujuan; Li, Sen; Wang, Yuanhao; Huang, Lei; Yu, Xiaofang 浏览/下载:0/0被引[WOS]:0被引[Scopus]:0影响因子:6.7期刊论文EI 评论分享收藏
[3] An integrated strategy for high-sensitive and multi-level glycoproteome analysis from low micrograms of protein samples 来源：JOURNAL OF CHROMATOGRAPHY A, 2019, 卷号: 1600, 页码: 46-54 作者： Gao, Weina; Li, Hongjie; Liu, Liping; Huang, Peiwu; Wang, Zhikun; et al. Adobe \| 浏览/下载:22/0被引[WOS]:11被引[Scopus]:8影响因子:3.8期刊论文SCIEI 评论分享收藏

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