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Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).","jscount":"1","jsurl":"/simple-search?field1=dc.contributor.author&rpp=10&accurate=true&advanced=false&sort_by=-1&isNonaffiliated=false&search_type=-1&query1=%2522Huang%252C%2BLei%2522&order=desc&&fq=dc.project.title_filter%3ASupporting%5C+matrixes%5C+play%5C+an%5C+important%5C+role%5C+in%5C+Cu%5C-based%5C+catalyst%5C%2FNORR.%5C+Commonly%5C+used%5C+supporting%5C+matrixes%5C+for%5C+Cu%5C-based%5C+catalysts%5C+include%5C+Ni%5C+foams%5C+%5C%28NF%5C%29%2C%5C+Cu%5C+foams%5C+%5C%28CF%5C%29%2C%5C+carbon%5C+felts%2C%5C+graphite%5C+felts%2C%5C+glassy%5C+carbon%5C+%5C%28GCE%5C%29%2C%5C+carbon%5C+clothes%5C+%5C%28CC%5C%29%2C%5C+and%5C+carbon%5C+paper%2C%5C+which%5C+protect%5C+and%5C+support%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%2C125%2C165%2C209%5C%5D.%5C+However%2C%5C+in%5C+NORR%2C%5C+researchers%5C+have%5C+focused%5C+on%5C+Cu%5C-based%5C+catalysts%2C%5C+ignoring%5C+the%5C+influence%5C+and%5C+role%5C+of%5C+supporting%5C+matrixes.%5C+Currently%2C%5C+only%5C+Li%27%27s%5C+team%5C+has%5C+published%5C+a%5C+paper%5C+on%5C+the%5C+effect%5C+of%5C+three%5C+different%5C+supporting%5C+matrixes%5C+%5C%28NF%2C%5C+CF%5C+and%5C+CC%5C%29%5C+on%5C+the%5C+NORR%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%5C%5D.%5C+They%5C+prepared%5C+three%5C+electrodes%2C%5C+Cu%40NF%2C%5C+Cu%40CF%5C+and%5C+Cu%40CC%2C%5C+by%5C+supporting%5C+Cu%5C-based%5C+catalysts%5C+onto%5C+NF%2C%5C+CF%5C+and%5C+CC%5C+by%5C+electrodeposition.%5C+Among%5C+them%2C%5C+the%5C+surface%5C+morphology%5C+of%5C+Cu%40NF%5C+showed%5C+a%5C+uniform%5C+dendrite%5C+structure.%5C+When%5C+CF%5C+and%5C+CC%5C+were%5C+used%5C+as%5C+support%2C%5C+agglomeration%5C+of%5C+Cu%5C-based%5C+catalysts%5C+occurred.%5C+In%5C+addition%2C%5C+electrochemical%5C+experiments%5C+and%5C+DFT%5C+showed%5C+that%5C+Ni%5C+atoms%5C+have%5C+strong%5C+adsorption%5C+capacity%5C+for%5C+H%2C%5C+and%5C+NF%5C+can%5C+introduce%5C+Ni%5C+atoms%5C+into%5C+Cu%5C-based%5C+catalysts%5C+to%5C+promote%5C+the%5C+generation%5C+of%5C+H%2C%5C+reduce%5C+the%5C+overpotential%2C%5C+and%5C+make%5C+NO%E2%88%92%5C+reduce%5C+rapidly%5C+through%5C+the%5C+H%5C+pathway.%5C+Therefore%2C%5C+the%5C+order%5C+of%5C+electrocatalytic%5C+activities%5C+of%5C+the%5C+Cu%5C+catalysts%5C+formed%5C+on%5C+the%5C+three%5C+supports%5C+is%5C+Cu%40NF%5C+%3E%5C+Cu%40CF%5C+%3E%5C+Cu%40CC.%5C+The%5C+reason%5C+for%5C+the%5C+superiority%5C+of%5C+Cu%40CF%5C+over%5C+Cu%40CC%5C+is%5C+the%5C+good%5C+electronic%5C+conductivity%5C+of%5C+CF.%5C+In%5C+summary%2C%5C+we%5C+can%5C+preliminarily%5C+conclude%5C+that%5C+supporting%5C+matrixes%5C+may%5C+affect%5C+the%5C+surface%5C+morphology%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+can%5C+influence%5C+the%5C+reaction%5C+path%5C+under%5C+specific%5C+conditions%5C+%5C%28Fig.%5C+5%5C%29.%5C+There%5C+is%5C+no%5C+relevant%5C+research%5C+on%5C+how%5C+supporting%5C+matrixes%5C+affect%5C+the%5C+morphology%2C%5C+structure%2C%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+what%5C+role%5C+they%5C+play%5C+in%5C+NORR.%5C+Meanwhile%2C%5C+there%5C+is%5C+a%5C+lack%5C+of%5C+relevant%5C+studies%5C+to%5C+distinguish%5C+between%5C+them.This%5C+work%5C+was%5C+financially%5C+supported%5C+by%5C+the%5C+National%5C+Natural%5C+Science%5C+Foundation%5C+of%5C+China%5C+%5C%28Project%5C+No.%5C+22266009%5C%29%5C%3B%5C+Guizhou%5C+Science%5C+and%5C+Technology%5C+Plan%5C+Project%5C+%5C%28Guizhou%5C+Science%5C+Support%5C+%5C%5B2024%5C%5D%5C+General%5C+118%5C%29%5C%3B%5C+Doctoral%5C+Research%5C+Fund%5C+of%5C+Guizhou%5C+Normal%5C+University%2C%5C+China%5C+%5C%28GZNUD%5C+%5C%5B2019%5C%5D6%5C%29."},{"jsname":"lastIndexed","jscount":"2025-04-25"}],"资助项目","dc.project.title_filter")'>资助项目

Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).","jscount":"1","jsurl":"/simple-search?field1=dc.contributor.author&rpp=10&accurate=true&advanced=false&sort_by=-1&isNonaffiliated=false&search_type=-1&query1=%2522Huang%252C%2BLei%2522&order=desc&&fq=dc.project.title_filter%3ASupporting%5C+matrixes%5C+play%5C+an%5C+important%5C+role%5C+in%5C+Cu%5C-based%5C+catalyst%5C%2FNORR.%5C+Commonly%5C+used%5C+supporting%5C+matrixes%5C+for%5C+Cu%5C-based%5C+catalysts%5C+include%5C+Ni%5C+foams%5C+%5C%28NF%5C%29%2C%5C+Cu%5C+foams%5C+%5C%28CF%5C%29%2C%5C+carbon%5C+felts%2C%5C+graphite%5C+felts%2C%5C+glassy%5C+carbon%5C+%5C%28GCE%5C%29%2C%5C+carbon%5C+clothes%5C+%5C%28CC%5C%29%2C%5C+and%5C+carbon%5C+paper%2C%5C+which%5C+protect%5C+and%5C+support%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%2C125%2C165%2C209%5C%5D.%5C+However%2C%5C+in%5C+NORR%2C%5C+researchers%5C+have%5C+focused%5C+on%5C+Cu%5C-based%5C+catalysts%2C%5C+ignoring%5C+the%5C+influence%5C+and%5C+role%5C+of%5C+supporting%5C+matrixes.%5C+Currently%2C%5C+only%5C+Li%27%27s%5C+team%5C+has%5C+published%5C+a%5C+paper%5C+on%5C+the%5C+effect%5C+of%5C+three%5C+different%5C+supporting%5C+matrixes%5C+%5C%28NF%2C%5C+CF%5C+and%5C+CC%5C%29%5C+on%5C+the%5C+NORR%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+%5C%5B38%5C%5D.%5C+They%5C+prepared%5C+three%5C+electrodes%2C%5C+Cu%40NF%2C%5C+Cu%40CF%5C+and%5C+Cu%40CC%2C%5C+by%5C+supporting%5C+Cu%5C-based%5C+catalysts%5C+onto%5C+NF%2C%5C+CF%5C+and%5C+CC%5C+by%5C+electrodeposition.%5C+Among%5C+them%2C%5C+the%5C+surface%5C+morphology%5C+of%5C+Cu%40NF%5C+showed%5C+a%5C+uniform%5C+dendrite%5C+structure.%5C+When%5C+CF%5C+and%5C+CC%5C+were%5C+used%5C+as%5C+support%2C%5C+agglomeration%5C+of%5C+Cu%5C-based%5C+catalysts%5C+occurred.%5C+In%5C+addition%2C%5C+electrochemical%5C+experiments%5C+and%5C+DFT%5C+showed%5C+that%5C+Ni%5C+atoms%5C+have%5C+strong%5C+adsorption%5C+capacity%5C+for%5C+H%2C%5C+and%5C+NF%5C+can%5C+introduce%5C+Ni%5C+atoms%5C+into%5C+Cu%5C-based%5C+catalysts%5C+to%5C+promote%5C+the%5C+generation%5C+of%5C+H%2C%5C+reduce%5C+the%5C+overpotential%2C%5C+and%5C+make%5C+NO%E2%88%92%5C+reduce%5C+rapidly%5C+through%5C+the%5C+H%5C+pathway.%5C+Therefore%2C%5C+the%5C+order%5C+of%5C+electrocatalytic%5C+activities%5C+of%5C+the%5C+Cu%5C+catalysts%5C+formed%5C+on%5C+the%5C+three%5C+supports%5C+is%5C+Cu%40NF%5C+%3E%5C+Cu%40CF%5C+%3E%5C+Cu%40CC.%5C+The%5C+reason%5C+for%5C+the%5C+superiority%5C+of%5C+Cu%40CF%5C+over%5C+Cu%40CC%5C+is%5C+the%5C+good%5C+electronic%5C+conductivity%5C+of%5C+CF.%5C+In%5C+summary%2C%5C+we%5C+can%5C+preliminarily%5C+conclude%5C+that%5C+supporting%5C+matrixes%5C+may%5C+affect%5C+the%5C+surface%5C+morphology%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+can%5C+influence%5C+the%5C+reaction%5C+path%5C+under%5C+specific%5C+conditions%5C+%5C%28Fig.%5C+5%5C%29.%5C+There%5C+is%5C+no%5C+relevant%5C+research%5C+on%5C+how%5C+supporting%5C+matrixes%5C+affect%5C+the%5C+morphology%2C%5C+structure%2C%5C+and%5C+catalytic%5C+performance%5C+of%5C+Cu%5C-based%5C+catalysts%5C+and%5C+what%5C+role%5C+they%5C+play%5C+in%5C+NORR.%5C+Meanwhile%2C%5C+there%5C+is%5C+a%5C+lack%5C+of%5C+relevant%5C+studies%5C+to%5C+distinguish%5C+between%5C+them.This%5C+work%5C+was%5C+financially%5C+supported%5C+by%5C+the%5C+National%5C+Natural%5C+Science%5C+Foundation%5C+of%5C+China%5C+%5C%28Project%5C+No.%5C+22266009%5C%29%5C%3B%5C+Guizhou%5C+Science%5C+and%5C+Technology%5C+Plan%5C+Project%5C+%5C%28Guizhou%5C+Science%5C+Support%5C+%5C%5B2024%5C%5D%5C+General%5C+118%5C%29%5C%3B%5C+Doctoral%5C+Research%5C+Fund%5C+of%5C+Guizhou%5C+Normal%5C+University%2C%5C+China%5C+%5C%28GZNUD%5C+%5C%5B2019%5C%5D6%5C%29."},{"jsname":"lastIndexed","jscount":"2025-04-25"}],"资助项目","dc.project.title_filter")'>

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Cu@CF > Cu@CC. The reason for the superiority of Cu@CF over Cu@CC is the good electronic conductivity of CF. In summary, we can preliminarily conclude that supporting matrixes may affect the surface morphology and catalytic performance of Cu-based catalysts and can influence the reaction path under specific conditions (Fig. 5). There is no relevant research on how supporting matrixes affect the morphology, structure, and catalytic performance of Cu-based catalysts and what role they play in NORR. Meanwhile, there is a lack of relevant studies to distinguish between them.This work was financially supported by the National Natural Science Foundation of China (Project No. 22266009); Guizhou Science and Technology Plan Project (Guizhou Science Support [2024] General 118); Doctoral Research Fund of Guizhou Normal University, China (GZNUD [2019]6).'>Supporting matrixes play an important role in...[1]

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[1] Privacy-Aware Sensor Network Via Multilayer Nonlinear Processing 来源：IEEE Internet of Things Journal, 2019, 卷号: 6, 期号: 6, 页码: 10834-10845 作者： He, Xin; Tay, Wee Peng; Huang, Lei; Sun, Meng; Gong, Yi 浏览/下载:12/0被引[WOS]:6被引[Scopus]:6影响因子:8.2期刊论文SCIEI 评论分享收藏
[2] Preparation, characterization, and application of Cu-based catalysts in electrocatalytic reduction of nitrate: A review 来源：Materials Today Chemistry, 2024, 卷号: 41 作者： Chen, Yujuan; Li, Sen; Wang, Yuanhao; Huang, Lei; Yu, Xiaofang 浏览/下载:0/0被引[WOS]:0被引[Scopus]:0影响因子:6.7期刊论文EI 评论分享收藏
[3] Nurse managers' perceptions and experiences of caring behavior for clinical nurses: a multicenter survey 来源：BMC NURSING, 2023, 卷号: 22, 期号: 1 作者： Liao, Lulu; Zhang, Fengjian; Zhang, Yan; Guan, Chunyan; Xu, Guihua; et al. 浏览/下载:0/0被引[WOS]:3被引[Scopus]:3影响因子:3.1期刊论文SCISSCI 评论分享收藏
[4] MaskDis R-CNN: An instance segmentation algorithm with adversarial network for herd pigs 来源：IET IMAGE PROCESSING, 2023, 卷号: 17, 页码: 3488-3499 作者： Tu, Shuqin; Zeng, Qiantao; Liu, Haofeng; Liang, Yun; Liu, Xiaolong; et al. 浏览/下载:1/0被引[WOS]:0被引[Scopus]:2影响因子:2.0期刊论文SCIEI 评论分享收藏
[5] Crucial Role of Tributary Bays in the Carbon Burial of Three Gorges Reservoir 来源：ACS ES&T WATER, 2024, 卷号: 4, 期号: 4 作者： Wang, Kai; Huang, Lei; He, Guojian; Liu, Yan; Xu, Song; et al. 浏览/下载:4/0被引[WOS]:0被引[Scopus]:0影响因子:4.8期刊论文ESCI 评论分享收藏
[6] Unraveling eutrophication controversies: Innovative strategies and holistic perspectives 来源：Critical Reviews in Environmental Science and Technology, 2024 作者： Hei, Pengfei; Yang, Tingting; Huang, Lei; Liu, Yan; Yang, Jing; et al. 浏览/下载:5/0被引[WOS]:0被引[Scopus]:0影响因子:11.4期刊论文EISCI 评论分享收藏

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